Comparing E228 - Potassium bisulphite vs E224 - Potassium metabisulphite
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Popular questions
How are bisulfite ions generated in the iodine clock reaction potassium iodate and sodium sulfite?
Bisulfite (HSO3−) comes either directly from dissolving potassium bisulfite (KHSO3 → K+ + HSO3−) or by protonation of sulfite from sodium sulfite in acidic solution (SO3^2− + H+ → HSO3−), which is the pH range used in the iodine clock.
How does sodium bisulfite and potassium iodate react to make iodine reaction with starch?
In acid, iodate (IO3−) oxidizes bisulfite (HSO3−) to sulfate while being reduced to iodide; once bisulfite is depleted, remaining iodate oxidizes iodide to iodine (I2), which then forms the blue complex with starch.
How does sodium bisulfite and potassium iodate react to make iodine reaction with starch equations?
Key steps (acidic medium): IO3− + 3 HSO3− → I− + 3 SO4^2− + 3 H+; then IO3− + 5 I− + 6 H+ → 3 I2 + 3 H2O; and while bisulfite remains, it removes iodine: I2 + HSO3− + H2O → 2 I− + HSO4− + 2 H+.
How long is potassium bisulfite good for?
Stored airtight in a cool, dry place, solid potassium bisulfite is typically usable for about 1–2 years; in solution it loses strength much faster (weeks to a few months) as it oxidizes to sulfate.
How most potassium bisulfite or metab?
Potassium metabisulfite (E224) is more commonly used because it’s more stable, but both it and potassium bisulfite (E228) release SO2; for dosing, KHSO3 is ~53% SO2 by weight and K2S2O5 is ~58%, so slightly less metabisulfite is needed to achieve the same SO2 level.
How much potassium metabisulfite per gallon of wine?
About 0.3 g per US gallon (≈50 ppm as SO2), or 1 Campden tablet per gallon; adjust to wine pH and confirm with a free SO2 test.
How much potassium metabisulfite per gallon of mead?
Start with ~0.3 g per US gallon (≈50 ppm as SO2), or 1 Campden tablet per gallon; mead’s typically higher pH may require more to reach the target molecular SO2, and stabilization often also uses potassium sorbate.
Is potassium metabisulfite harmful?
At permitted food levels it’s generally considered safe, but sulfites can trigger asthma or allergic‑like reactions in sensitive individuals; the powder/solutions are irritating, so avoid inhalation and skin/eye contact.
When to add potassium metabisulfite to wine?
Add at crush to limit wild microbes and oxidation, then maintain appropriate free SO2 after fermentation during aging/racking and just before bottling based on pH.
How much potassium metabisulfite per gallon?
About 0.3 g per US gallon (≈50 ppm as SO2), or 1 Campden tablet per gallon; measure free SO2 and adjust for your beverage’s pH.